tert-Butyl nitrite
- Product Name
- tert-Butyl nitrite
- CAS No.
- 540-80-7
- Chemical Name
- tert-Butyl nitrite
- Synonyms
- t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;ert-buty nitrite;t-Buthyl nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
- CBNumber
- CB6853772
- Molecular Formula
- C4H9NO2
- Formula Weight
- 103.12
- MOL File
- 540-80-7.mol
tert-Butyl nitrite Property
- Boiling point:
- 61-63 °C(lit.)
- Density
- 0.867 g/mL at 25 °C(lit.)
- vapor pressure
- 13.466kPa at 25℃
- refractive index
- n20/D 1.368(lit.)
- Flash point:
- −10 °F
- storage temp.
- 2-8°C
- solubility
- alcohol: very soluble(lit.)
- form
- Liquid
- color
- Clear yellow
- Water Solubility
- slightly soluble
- Merck
- 14,1583
- BRN
- 1209339
- LogP
- 2.24 at 20℃
- CAS DataBase Reference
- 540-80-7(CAS DataBase Reference)
- NIST Chemistry Reference
- (CH3)3CONO(540-80-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 20370
- Product name
- tert-Butyl nitrite
- Purity
- technical, ≥90% (GC)
- Packaging
- 100mL
- Price
- $92
- Updated
- 2024/03/01
- Product number
- 20370
- Product name
- tert-Butyl nitrite
- Purity
- technical, ≥90% (GC)
- Packaging
- 500mL
- Price
- $323
- Updated
- 2024/03/01
- Product number
- N0357
- Product name
- tert-Butyl Nitrite
- Purity
- >90.0%(GC)
- Packaging
- 25mL
- Price
- $65
- Updated
- 2024/03/01
- Product number
- N0357
- Product name
- tert-Butyl Nitrite
- Purity
- >90.0%(GC)
- Packaging
- 250mL
- Price
- $392
- Updated
- 2024/03/01
- Product number
- L16135
- Product name
- tert-Butyl nitrite
- Purity
- tech. 90%
- Packaging
- 25g
- Price
- $35.4
- Updated
- 2023/06/20
tert-Butyl nitrite Chemical Properties,Usage,Production
Chemical Properties
clear yellow liquid
Uses
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
Uses
Jet propellant.
General Description
tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.
Purification Methods
If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]
tert-Butyl nitrite Preparation Products And Raw materials
Raw materials
Preparation Products
tert-Butyl nitrite Suppliers
View Lastest Price from tert-Butyl nitrite manufacturers
- Product
- Tert-Butyl nitrite 540-80-7
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1Kg
- Purity
- 99.99%
- Supply Ability
- 20 tons
- Release date
- 2024-04-10
- Product
- t-butyl nitrite 540-80-7
- Price
- US $8.00-0.80/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-22
- Product
- tert-Butyl nitrite 540-80-7
- Price
- US $50.00/KG
- Min. Order
- 25KG
- Purity
- 98%
- Supply Ability
- 200 tons
- Release date
- 2020-07-14